全文获取类型
收费全文 | 732434篇 |
免费 | 92697篇 |
国内免费 | 119819篇 |
专业分类
化学 | 498453篇 |
晶体学 | 7992篇 |
力学 | 38240篇 |
综合类 | 13500篇 |
数学 | 80000篇 |
物理学 | 306765篇 |
出版年
2024年 | 2884篇 |
2023年 | 11084篇 |
2022年 | 12922篇 |
2021年 | 10380篇 |
2020年 | 10284篇 |
2019年 | 16017篇 |
2018年 | 17701篇 |
2017年 | 13826篇 |
2016年 | 15342篇 |
2015年 | 15973篇 |
2014年 | 26404篇 |
2013年 | 23361篇 |
2012年 | 55816篇 |
2011年 | 70236篇 |
2010年 | 31274篇 |
2009年 | 27196篇 |
2008年 | 60591篇 |
2007年 | 60560篇 |
2006年 | 61993篇 |
2005年 | 58091篇 |
2004年 | 50062篇 |
2003年 | 40139篇 |
2002年 | 35878篇 |
2001年 | 27851篇 |
2000年 | 29721篇 |
1999年 | 15048篇 |
1998年 | 8998篇 |
1997年 | 7037篇 |
1996年 | 12293篇 |
1995年 | 10411篇 |
1994年 | 11574篇 |
1993年 | 12537篇 |
1992年 | 11861篇 |
1991年 | 7553篇 |
1990年 | 7402篇 |
1989年 | 6614篇 |
1988年 | 7141篇 |
1987年 | 6650篇 |
1986年 | 6419篇 |
1985年 | 5966篇 |
1984年 | 3738篇 |
1983年 | 3219篇 |
1982年 | 2567篇 |
1981年 | 2030篇 |
1980年 | 1413篇 |
1979年 | 924篇 |
1978年 | 571篇 |
1966年 | 372篇 |
1965年 | 449篇 |
1948年 | 903篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The title compound 17(S)-methyl-13β-hydroxyl-14(R),20(S)-epoxy-pregn-4-en-3-one was synthesized by an improved tandem reaction, and its structure was determined by IR, NMR, HR MS and X-ray single-crystal diffraction. The crystal belongs to orthorhombic, space group P212121 with a = 10.55248(15), b = 12.14700(16), c = 14.56841(18) ?, V = 1867.39(4) ?3, Z = 4, Dc= 1.175 g/cm3, μ= 0.604 mm-1, F(000) = 720, the final R = 0.0400 and w R = 0.1072 for 3610 observed reflections with I 2σ(I). 相似文献
992.
A rigid supramolecular polymer was constructed in aqueous solution via cucurbit[8]uril(CB[8]) host recognition with a rigid monomer containing an azobenzene unit and two 4,4'-bipyridin-1-ium(BP)moieties in the two ends, which also exhibited photo-responsiveness owing to the photoinduced trans–cis isomerization of azobenzene group. 相似文献
993.
Signal distortion due to the non-uniform response of the detector degrades the measurement accuracy of most metrology instruments. In this Letter, we report a newly developed calibration source system for reference-based non-uniformity correction using a laser source, a fiber, and a diffusive module. By applying the Monte Carlo simulation, we show that the transmittance of the system highly depends on the cavity reflection of the diffusive module. We also demonstrate the use of this system to achieve a flat field at a very low non-uniformity(less than 0.2%) with proper illumination intensity, which most costly commercial integrating sphere systems traditionally cannot provide. 相似文献
994.
In the present research, hierarchical structure observation and mechanical property characterization for a type of biomaterial are carried out. The investigated biomaterial is Hyriopsis cumingii, a typical limnetic shell, which consists of two different structural layers, a prismatic "pillar"structure and a nacreous "brick and mortar" structure. The prismatic layer looks like a "pillar forest" with variationsection pillars sized on the order of several tens of microns.The nacreous material looks like a "brick wall" with bricks sized on the order of several microns. Both pillars and bricks are composed of nanoparticles. The mechanical properties of the hierarchical biomaterial are measured by using the nanoindentation test. Hardness and modulus are measured for both the nacre layer and the prismatic layer, respectively.The nanoindentation size effects for the hierarchical structural materials are investigated experimentally. The results show that the prismatic nanostructured material has a higher stiffness and hardness than the nacre nanostructured material.In addition, the nanoindentation size effects for the hierarchical structural materials are described theoretically, by using the trans-scale mechanics theory considering both strain gradient effect and the surface/interface effect. The modeling results are consistent with experimental ones. 相似文献
995.
997.
本文,我们结合统计过程控制方法,使用一种新的统计量用于在样本数量不充足的情况下监测高维数据。统计量利用样本协方差规范化技术避免协方差矩阵的奇异性,同时采用软阈值技术来挑选多维数据中重要的维度进行监测以减少监测噪音。本文在提出统计量后用matlab随机产生各种维度的高维数据样本进行仿真分析,并将该统计量与基于Hotelling T~2并采取广义逆矩阵的统计量进行比较。结果表明,本文使用的统计量的监测效果优于采取广义逆矩阵的方法。本文提出的方法可以应用于多指标产品生产的快速异常检测,特别是难以得到大量检测数据的产品,如检测需要破坏产品本身或者检测成本太高的产品。 相似文献
998.
水质评价涉及属性权与熵权两种权重.熵权表征因子的分类能力,由因子的隶属度向量通过计算信息熵确定.属性权表征因子重要性程度的差异,用途是使不同因子的隶属度具有"可比性",但定权方法众说不一.指出,因子重要性程度差异源于因子属性与因子取值无关,并且表征这种差异等同于对因子接重要性排序.AHP的比例标度判断矩阵为因子排序提供了合理的数据条件,但基于"一致性检验"的特征根排序法受到质疑;FAHP也因没有彻底摆脱"一致性",所以建立的排序方法有局限性.为此,通过标度变换将比例标度转化为评分标度,利用评分标度的可加性把判断矩阵中由评分标度确定的因子的序关系转化为因子排序.由此建立不受"一致性"干扰的定权方法. 相似文献
999.
基于实验得到的单晶结构建立了理论计算的结构模型,旨在用计算结果揭示实验所获得结构的微观驱动力,即弱相互作用的重要模式.通过对实验结构的异构化处理,建立异构体模型并进行比对,可以给出实验结构在能量上的优势.采用密度泛函方法对BIPy的2种同晶异形体I(实验获得的单晶结构)和II(根据I的结构设计的异构体)与水分子之间的氢键相互作用进行了计算.结果表明,BIPy-I在能量上具有明显优势,进一步证明了水分子在水分子夹中更适合作为氢键的受体.虽然BIPy-II构型也处于势能面上的稳定点,但是实验无法得到其单晶结构.因此,从BIPy-I构型中所观察到的N-H…O氢键模式是优势作用模式. 相似文献
1000.
Mass concentration and isotopic values δ13C and 14C are presented for the water-insoluble refractory carbon(WIRC) component of total suspended particulates(TSP),collected weekly during 2003,as well as from October 2005 to May 2006 at the WMO-GAW Mt.Waliguan(WLG) site.The overall average WIRC mass concentration was(1183±120)ng/m3(n = 79),while seasonal averages were 2081 ±1707(spring),454±205(summer),650±411(autumn),and 1019±703(winter) ng/m3.Seasonal variations in WIRC mass concentrations were consistent with black carbon measurements from an aethalometer,although WIRC concentrations were typically higher,especially in winter and spring.The δ13C PDB value(-25.3 ± 0.8)%.determined for WIRC suggests that its sources are C3 biomass or fossil fuel combustion.No seasonal change in δ13C PDB was evident.The average percent Modern Carbon(pMC) for 14C in WIRC for winter and spring was(67.2 ± 7.7)%(n = 29).Lower pMC values were associated with air masses transported from the area east of WLG,while higher pMC values were associated with air masses from the Tibetan Plateau,southwest of WLG.Elevated pMC values with abnormally high mass concentrations of TSP and WIRC were measured during a dust storm event. 相似文献